Bis[1-(3,5-di-tert-butyl-2-hydroxy­benz­yl)-3-isopropyl­imidazolium] penta­chlorido(tetra­hydro­furan)samarate(III)–tetrahydrofuran–toluene (1/1/1)

نویسندگان

  • Zhiguo Wang
  • Siman Liu
  • Qinquan Bian
چکیده

The title compound, (C(21)H(33)N(2)O)(2)[SmCl(5)(C(4)H(8)O)]·C(7)H(8)·C(4)H(8)O, has a layered structure in which each distorted octa-hedral [SmCl(5)(THF)](2-) unit (THF is tetra-hydro-furan) is capped by two cations. The central metal Sm(III) atom of the [SmCl(5)(THF)](2-) anionic unit is coordinated by five Cl atoms and one THF O atom, forming a distorted octa-hedral geometry. The crystal structure displays C-H⋯Cl and O-H⋯Cl hydrogen bonding. The structure exhibits disorder of the solvent.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010